|
|
validamycin_A + 2-oxoglutarate + O2 <=> validamycin_B + succinate + CO2
|
1.14.11.52
validamycin A dioxygenase
|
–
|
| |
BRENDA:
BR51692
KEGG:
R11340
MetaCyc:
RXN-17381
|
|
|
|
L-glutamate + validone_7-phosphate <=> 2-oxoglutarate + validamine_7-phosphate
|
2.6.1.M1
|
–
|
| |
MetaCyc:
RXN-17378
|
|
|
|
valienone + ATP <=> H+ + valienone_7-phosphate + ADP
|
2.7.1.214
C7-cyclitol 7-kinase
|
–
|
| |
BRENDA:
BR51758
KEGG:
R11234
MetaCyc:
RXN-9144
|
|
|
|
alpha-D-sedoheptulopyranose_7-phosphate <=> 2-epi-5-epi-valiolone + phosphate
|
4.2.3.152
2-epi-5-epi-valiolone synthase
|
–
|
| |
BRENDA:
BR51246
KEGG:
R10937
MetaCyc:
RXN-9140
|
|
|
|
validone_7-phosphate + NAD+ <=> valienone_7-phosphate + NADH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-9146
|
|
|
|
5-epi-valiolone <=> valienone + H2O
|
4.2.1
|
–
|
| |
KEGG:
R11233
MetaCyc:
RXN-9142
|
|
|
|
valienone_7-phosphate + reduced_acceptor <=> valienol_7-phosphate + acceptor
|
1.1.1
|
–
|
| |
MetaCyc:
RXN-17376
|
|
|
|
UDP-glucose + validoxylamine_A <=> validamycin_A + UDP + H+
|
2.4.1.338
validoxylamine A glucosyltransferase
|
–
|
| |
BRENDA:
BR51706
KEGG:
R11241
MetaCyc:
RXN-9148
|
|
|
|
validoxylamine_A_7''-phosphate + H2O <=> validoxylamine_A + phosphate
|
3.1.3.101
validoxylamine A 7'-phosphate phosphatase
|
–
|
| |
BRENDA:
BR51715
KEGG:
R11240
MetaCyc:
RXN-17380
|
|
|
|
valienol_7-phosphate <=> valienol_1-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11499
MetaCyc:
RXN-17383
|
|
|
|
GDP-valienol + validamine_7-phosphate <=> validoxylamine_A_7''-phosphate + GDP + H+
|
2.5.1.135
validamine 7-phosphate valienyltransferase
|
–
|
| |
BRENDA:
BR51891
KEGG:
R11497
MetaCyc:
RXN-17379
|
|
|
|
GTP + valienol_1-phosphate + H+ <=> GDP-valienol + diphosphate
|
2.7.7.91
valienol-1-phosphate guanylyltransferase
|
–
|
| |
BRENDA:
BR51761
KEGG:
R11402
MetaCyc:
RXN-17377
|
|
|
|
2-epi-5-epi-valiolone <=> 5-epi-valiolone
|
5.1.3.33
2-epi-5-epi-valiolone epimerase
|
–
|
| |
BRENDA:
BR51250
KEGG:
R11079
MetaCyc:
RXN-9141
|
|
